Chem 3240 · Appendix A.2

\cos^2\theta + \sin^2\theta = 1
Angle sum, the workhorse
\sin(A \pm B) = \sin A\cos B \pm \cos A\sin B
\cos(A \pm B) = \cos A\cos B \mp \sin A\sin B
Power reduction, a square becomes a single cosine
\sin^2\theta = \tfrac{1}{2}(1 - \cos 2\theta), \qquad \cos^2\theta = \tfrac{1}{2}(1 + \cos 2\theta)
Small angles in radians, the first Taylor terms
\sin\theta \approx \theta, \qquad \cos\theta \approx 1 - \tfrac{1}{2}\theta^2

z = x + iy, \qquad x = \operatorname{Re} z,\ \ y = \operatorname{Im} z


Locate z by its distance r and angle \phi
x = r\cos\phi, \qquad y = r\sin\phi
e^{i\phi} = \cos\phi + i\sin\phi
z = r(\cos\phi + i\sin\phi) = r\,e^{i\phi}
Write z = -4 + 4i in polar form.
r = \sqrt{(-4)^2 + 4^2} = 4\sqrt{2}, \qquad \phi = \frac{3\pi}{4}
z = 4\sqrt{2}\;e^{i\,3\pi/4}
arctan2(y, x), not from \arctan(y/x)atan sees -4/4 and 4/{-4} as one ratio and always answers in quadrant I or IV; atan2 reads both signs
(r_1 e^{i\phi_1})(r_2 e^{i\phi_2}) = r_1 r_2\, e^{i(\phi_1 + \phi_2)}
Find (3 + 4i)(1 - 2i), then \left(2e^{i\pi/6}\right)\left(3e^{i\pi/3}\right).
(3 + 4i)(1 - 2i) = 3 - 6i + 4i - 8i^2 = 11 - 2i
\left(2e^{i\pi/6}\right)\left(3e^{i\pi/3}\right) = 6\,e^{i(\pi/6 + \pi/3)} = 6\,e^{i\pi/2} = 6i
z and e^{i\phi} z: the length never changes, only the angle
{
const z = {re: 1.3, im: 0.5};
const w = {re: Math.cos(phi) * z.re - Math.sin(phi) * z.im, im: Math.sin(phi) * z.re + Math.cos(phi) * z.im};
const R = Math.hypot(z.re, z.im);
const circle = d3.range(0, 6.3, 0.05).map(t => ({x: R * Math.cos(t), y: R * Math.sin(t)}));
const a0 = Math.atan2(z.im, z.re);
const arc = d3.range(0, 1.0001, 0.02).map(s => ({x: 0.5 * Math.cos(a0 + s * phi), y: 0.5 * Math.sin(a0 + s * phi)}));
return Plot.plot({
width: 440, height: 440, aspectRatio: 1,
x: {domain: [-2, 2], label: "Real", ticks: 5}, y: {domain: [-2, 2], label: "Imaginary", ticks: 5},
marks: [
Plot.line(circle, {x: "x", y: "y", stroke: "#bbb", strokeDasharray: "4,4"}),
Plot.ruleX([0], {stroke: "#333"}), Plot.ruleY([0], {stroke: "#333"}),
Plot.arrow([{x1: 0, y1: 0, x2: z.re, y2: z.im}], {x1: "x1", y1: "y1", x2: "x2", y2: "y2", stroke: "#e67e22", strokeWidth: 3}),
Plot.arrow([{x1: 0, y1: 0, x2: w.re, y2: w.im}], {x1: "x1", y1: "y1", x2: "x2", y2: "y2", stroke: "#107895", strokeWidth: 3}),
Plot.line(arc, {x: "x", y: "y", stroke: "#C8102E", strokeWidth: 2}),
Plot.text([{x: z.re + 0.15, y: z.im + 0.1, t: "z"}], {x: "x", y: "y", text: "t", fill: "#e67e22", fontSize: 18}),
Plot.text([{x: w.re + 0.15, y: w.im + 0.1, t: "e^(iφ) z"}], {x: "x", y: "y", text: "t", fill: "#107895", fontSize: 18})
]
});
}
e^{i\omega t} = \cos\omega t + i\sin\omega t
\bar{z} = x - iy = r\,e^{-i\phi}, \qquad |z|^2 = \bar{z}\,z = x^2 + y^2 = r^2
\cos\phi = \frac{e^{i\phi} + e^{-i\phi}}{2}, \qquad \sin\phi = \frac{e^{i\phi} - e^{-i\phi}}{2i}
Find |7 + 24i|, then divide 3 + 4i by 1 - 2i.
|7 + 24i| = \sqrt{49 + 576} = \sqrt{625} = 25
\frac{3 + 4i}{1 - 2i} = \frac{(3 + 4i)(1 + 2i)}{(1 - 2i)(1 + 2i)} = \frac{-5 + 10i}{5} = -1 + 2i
Each cosine is the shadow of a turning arrow, \cos\theta = \operatorname{Re}\,e^{i\theta}
\cos\theta + \cos(\theta + \phi) = \operatorname{Re}\,e^{i\theta} + \operatorname{Re}\,e^{i\theta}e^{i\phi} = \operatorname{Re}\big[e^{i\theta} + e^{i\theta}e^{i\phi}\big]
\cos\theta + \cos(\theta + \phi) = \operatorname{Re}\big[e^{i\theta}\,(1 + e^{i\phi})\big]

|1 + e^{i\phi}| = 2\left|\cos(\phi/2)\right|
\frac{\partial}{\partial x}\,e^{i(kx - \omega t)} = ik\,e^{i(kx - \omega t)}, \qquad \frac{\partial}{\partial t}\,e^{i(kx - \omega t)} = -i\omega\,e^{i(kx - \omega t)}
e^{i\phi} = \cos\phi + i\sin\phi turns trigonometry into exponentials: multiplying by e^{i\phi} rotates without stretching, \bar z z = |z|^2 turns any complex number into a real length, and adding waves becomes adding arrows.
Chem 3240 · Quantum Mechanics